PRIMARY CELL
It essentially consists of two dissimilar conducting
electrodes immersed in a liquid called electrolyte which acts chemically on one
of the two electrodes more readily than on the other. By using the energy
released by chemical action, electrons are shifted from one electrode to
another thereby creating a potential difference between the two electrodes. The
value of total potential difference created between the electrodes, when the
cell is not connected to an external circuit, is known as its electromotive
force.
Now, every cell has some internal resistance which depends
upon the construction and condition of the cell. The internal resistance
depends on the area of electrodes, the distance between the electrodes, the
temperature, strength and density of the electrolyte. When the cell supplies
current to an external circuit, there is always some internal voltage drop due
to this internal resistance. Hence, the voltage available for external circuit
is decreased by this amount. The net voltage available at the terminals for
external circuit is known as the terminal potential difference.
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